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Beilstein J. Org. Chem. 2021, 17, 2915–2921, doi:10.3762/bjoc.17.199
Graphical Abstract
Figure 1: Structure of the repeating unit of the lipopolysaccharide of Providencia stuartii O49 serotype.
Scheme 1: Retrosynthetic analysis for the synthesis of the target trisaccharide 1.
Scheme 2: Synthesis of the monosaccharide building blocks 3, 6, and 7.
Scheme 3: Linear synthesis of trisaccharide derivative 2.
Scheme 4: Synthesis of ᴅ-galactose donor 12.
Scheme 5: One-pot synthesis of trisaccharide derivative 2.
Scheme 6: Synthesis of trisaccharide derivative 1.
Beilstein J. Org. Chem. 2020, 16, 140–148, doi:10.3762/bjoc.16.16
Figure 1: Biologically and medicinally important 3-alkenylindoles.
Scheme 1: a) Previous and b) present work related to the synthesis of 3-alkenylindoles.
Scheme 2: Substrate scope for the C–H alkenylation of the indoles 1. Reaction conditions: 1 (1 mmol), 2 (2 mm...
Scheme 3: a) Three-phase test to determine a homogeneous or heterogeneous catalytic mechanism of action for t...
Scheme 4: Probable catalytic mechanism for the transformation of 1a by the RuNC.